Methyl chloroformate, with cas number of 79221, can be called carbonochloridic acid, methyl ester. See actual entry in rtecs for complete information. Section 5 fire fighting measures general information. The test material was completely soluble in ethanol. Search results for methyl chloroformate at sigmaaldrich. In the absence of s9, the average numbers of mutants in controls in strains ta98, ta100, ta1535 all experiments, and ta1537 were 23, 149, 1618, and 10, respectively. Effects reported in humans due to acute shortterm inhalation exposure to methyl chloroform include hypotension, mild hepatic effects, and central nervous system cns depression. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Methyl chloroformate is incompatible with water, strong oxidizing agents, alcohols, bases. Address 1 north transit road, lockport, ny 14094 usa. Material safety data sheet methyl acetate section 1 chemical product and company identification msds name.
Methyl chloroformate cas number 79221 eu number 2011873 index number. If this is impossible then take the following precautions. India veritas house, 70 mint road, fort, mumbai 400 001. Aldrich m35304 page 1 of 8 sigmaaldrich safety data sheet version 5. Safety data sheet chloromethyl chloroformate date prepared. First aid measures general advice consult a physician. Calarp program combined 1 list of chemicals and threshold. Get here the database of methyl chloroformate cas no 79221, methyl chloroformate manufacturers, suppliers and exporters. Manufacturer importer supplier distributor information manufacturer vandemark chemical inc.
The methyl chloroformate manufacturing companies are offering top quality products at suitable price. Chlorocarbonic acid, methyl ester chloroformic acid, methyl ester methyl chlorocarbonate evacuate. Breathing methyl chloroformate can irritate the lungs. The waste framework directive aims to protect the environment and human health from the generation and management of waste and to. Methyl chloroformate is incompatible with water, strong oxidizing agents, alcohols, bases including amines. Methyl chloroformate, 79221, acid halides, c2h3clo2 by loba chemie, india. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Methyl chloroformate mcf is generally used for the derivatization of functional groups such as carboxylic acids, amines, and phenols. To activate 3acylpyridines for nucleophilic addition with alkynyltin reagents to form 2,3disubstituted 1,2dihydropyridines. Our msds database is an easy to use, do it yourself tool, and best of all. Cas number, unna number, dot hazard label, uscg chris code. Articles of methyl chloroformate are included as well. Methyl and ethyl chloroformate derivatizations for compoundspeci. This material does not contain any hazardous air pollutants.
First aid measures as this product is a gas, refer to the inhalation section. Methyl chloroformate carbonochloridic acid, methylester 79221 5,000. Sds of ethyl chloroformate, safety data sheets, cas 5414. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Keep unnecessary people away, isolate hazard area and deny. Structure, properties, spectra, suppliers and links for. Osha no component of this product present at levels greater. In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment. Methyl chloroformate manufacturers, suppliers and exporters. Methyl chloroformate can affect you when breathed in. Sds of methyl chloroformate, safety data sheets, cas 79221.
Methyl chloroformate mhc cautionary response information common synonyms liquid colorless to light yellow unpleasant odor sinks and reacts in water. Show this safety data sheet to the doctor in attendance. Reaction of 2aminothiazoles 1ab with various alkyl chloroformates 2ad, namely methyl chloroformate, ethyl chloroformate, propyl chloroformate and isobutyl chloroformate under dry conditions and in presence of pyridine 33 or triethylamine as the basic catalyst, afforded the corresponding carbamates 3ae. Identification of the substancemixture and of the companyundertaking product name. Methyl formate revision date 25apr2019 general advice if symptoms persist, call a physician. Methyl chloroformate 79221 tokyo chemical industry co. As in any fire, wear a selfcontained breathing apparatus in pressuredemand, mshaniosh approved or equivalent, and full protective. There was no mutagenic effect of test material in the presence or absence of s9. Prevent further leakage or spillage if safe to do so.
Page 3 of 7 containers with water from unmanned hose holder or monitor nozzles until well after fire is out. As in any fire, wear a selfcontained breathing apparatus in pressuredemand, mshaniosh approved. The substance identity section is calculated from substance identification information from all echa databases. Calarp program combined 1 list of chemicals and threshold quantities tq chemical name. Methyl parathion 4 ec page 1 of 7 msds revision date ddmmyyyy.
Methyl chloroformate hazard summary methyl chloroformate. Methyl chloroformate is a highly corrosive chemical and contact can severely irritate and burn the skin and eyes with possible eye damage. Decomposes slowly in water to yield methanol, hcl, and co2. Methods in molecular biology methods and protocols, vol 1198. Methyl chloroform 1,1,1trichloroethane 71556 hazard summary methyl chloroform is used as a solvent and in many consumer products. Chemical resistant protective gloves, butyl rubber, consult with glove manufacturer for testing data. Safety data sheet methyl chloroformate revision date. Methyl chloroformate is on the hazardous substance. Methyl chloroformate ch3ococl or c2h3clo2 cid 6586 structure, chemical names. This fact sheet is a summary source of information of all. Methyl chloroformate article about methyl chloroformate by. Methyl chloroformate appears as a colorless liquid with a pungent odor.
This material does not contain any class 1 ozone depletors. Methyl chloroformate is used in organic synthesis for the introduction of the methoxycarbonyl functionality to a suitable nucleophile i. Article methyl and ethyl chloroformate derivatizations for. Methyl 4hydroxybenzoate phydroxybenzoic acid methyl ester formula. Identification product identifier benzyl chloroformate other means of identification not available. Palmitic acid methyl ester safety data sheet supersedes revision. Quantitative analysis of amino and organic acids by methyl. It is a colorless liquid with a pungent odor, it is corrosive to metals and tissue. Breathing methyl chloroformate can irritate the nose and throat. Methyl chloroformate is the methyl ester of chloroformic acid and is an oily liquid with a color that is anywhere from yellow to colorless. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas.